http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-S6259248-A

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filingDate 1985-09-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ca226eb0d0d15d3c0b92218bc3616a61
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publicationDate 1987-03-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S6259248-A
titleOfInvention Production of n-vinylformamide
abstract PURPOSE: To obtain the titled compound in high yield, by etherifying N-(α- hydroxyethyl)formamide with a polyhydric alcohol, heating the ether compound under reduced pressure in a liquid phase and carrying out thermal decomposition while distilling away N-vinylformamide. n CONSTITUTION: N-(α-Hydroxyethyl)formamide is etherified with a polyhydric alcohol such as dihydric alcohol, etc., in the presence of a catalyst of a mineral acid such as sulfuric acid, etc., at 0W100°C for 0.5W5hr, heated in a liquid phase at ≤200Hg reduced pressure at 90W200°C and thermal decomposition is carried out while distilling away formed N-vinylformamide, to give the aimed compound. n EFFECT: A small amount of by-products such as resin component, etc., is formed, the temperature of the thermal decomposition is lower than a conventional gaseous-phase method so this process is advantageous with respect to heat energy. There is not such problem in operation as clogging of a reaction tube with resin like a gaseous-phase method and this process is an industrially improved method. n USE: A polymerizable monomer to provide a water-soluble polymer as a flocculant. n COPYRIGHT: (C)1987,JPO&Japio
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http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-H076658-A
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4996322-A
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priorityDate 1985-09-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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Total number of triples: 34.