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filingDate 1986-06-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_04f8330435c3de57393a5bb3a817e904
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publicationDate 1987-12-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S62283128-A
titleOfInvention Poly(allylsilsesquioxane) and production thereof
abstract PURPOSE:To obtain a poly(allylsilsesquioxane) soluble in organic solvent, by hydrolyzing allyltrichlorosilane with sodium bicarbonate and carrying out the polycondensation of the resultant prepolymer using a tertiary amine. CONSTITUTION:The objective poly(allylsilsesquioxane) of formula can be produced by (1) hydrolyzing allyltrichlorosilane with sodium bicarbonate in a mixture of an ether solvent (e.g. diethyl ether) and water and (2) subjecting the resultant prepolymer to polycondensation with a tertiary amine (e.g. triethylamine) in a ketone solvent (e.g. methyl isobutyl ketone). A film of the obtained poly(allylsilsesquioxane) is resistant to thermal curing even in the absence of silylation treatment and keeps the solubility in organic solvent. It is suitable as a resist for electron radiation, etc.
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Total number of triples: 37.