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filingDate 1986-03-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_578db5838d1734490d460c1de53b4c0c
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publicationDate 1987-09-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S62215580-A
titleOfInvention Novel tetrahydropyranyl ether
abstract NEW MATERIAL:1-(Tetrahydropyran-2-yloxy)-11-dodecene of formula I. n USE: A synthetic intermediate of 11-dodecenyl acetate, a major component of the sex pheromone of tea leaf folder (Homona magnanima DIAKONOFF). The use of the compound enables the large-amount production of the pheromone. n PREPARATION: Only one hydroxyl in 1,12-dodecanediol of formula II is halogenated according to a usual manner to give 12-halododecanol of formula III (X is halogen). The remaining hydroxyl is protected with a tetrahydropyranyl group to form 12-halo-1-(tetrahydropyran-2-yloxy)dodecane. The product is allowed to react with a base such as potassium t-butoxide in an organic solvent such as dimethyl sulfoxide at room temperature, when needed, at 0°C to the boiling point of the solvent to give the compound of formula I. n COPYRIGHT: (C)1987,JPO&Japio
priorityDate 1986-03-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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