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Outgoing Links

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classificationCPCAdditional http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y02P20-52
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C67-00
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filingDate 1986-03-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_bc73a53703b5cdb6582ae13ea7614f2c
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publicationDate 1987-09-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S62207242-A
titleOfInvention Production of bicyclo(3.3.0)octane compound
abstract PURPOSE: To efficiently obtain the titled compound, by treating a readily available 2-alkoxycarbonyl-3-substituted cyclopentanone as a raw material compound with an alkali metal hydride in an inert solvent and subjecting the resultant compound to intramolecular cyclization reaction. n CONSTITUTION: A cyclopentanone derivative expressed by formula I (R is 1W5C alkyl or 3W6C alkenyl; X is halogen; the double bond indicates the E-isomer, Z-isomer or E/Z mixture in any proportion), e.g. a compound expressed by formula II, etc., is treated with an alkali metal hydride, e.g. lithium hydride, etc., in an inert solvent to give a bicyclo[3.3.0]octane expressed by formula III, e.g. a compound expressed by formula IV, which is, together with a lithium halide, heat-treated in a polar inert solvent to afford the aimed bicyclo[3.3.0]octane expressed by formula V (A is H or COOR). n USE: An intermediate for prostaglandins. n COPYRIGHT: (C)1987,JPO&Japio
priorityDate 1986-03-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 26.