http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-S6219582-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_02ff914937eb6ceaee5ca69cc56cbfa7 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D333-38 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D333-32 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D333-68 |
filingDate | 1985-07-19-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_55c8de3080ec5360d8cfeeb6bddcfefc http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_cc0be39762b2e8d64cf3406d199a152a |
publicationDate | 1987-01-28-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | JP-S6219582-A |
titleOfInvention | Production of gamma-thiobutyrolactone derivative |
abstract | PURPOSE: To obtain simply in high yield a compound useful as a germicide, an anti-inflammatory agent, an activator for polymerization, etc., by reacting thiirane with an active methylene compound in the presence of a strong base. n CONSTITUTION: A thiirane shown by the formula I (R 1 is alkyl, aryl, or H; R 2 and R 3 are alkyl or H) is reacted with an active methylene compound shown by the formula II (R 4 is alkyl; R 5 is alkyl or alkoxy) in the presence of a base (e.g., sodium ethoxide) in a solution of an alkali catalyst (e.g., sodium hydride) in a solvent such as ethanol, etc., at room temperature or under heating to give the aimed compound shown by the formula III or formula IV. The compound shown by the formula I is easily synthesized from a corresponding epoxide by the use of thiourea or potassium thiocyanate and the compound shown by the formula II is inexpensively on the market and easily obtainable. n COPYRIGHT: (C)1987,JPO&Japio |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5242945-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-7030037-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5420153-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5366993-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5468774-A |
priorityDate | 1985-07-19-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 34.