http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-S62129253-A
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_2f8cfa5aee4410611b5c562275c9f8e3 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C67-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B53-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B31-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C205-56 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C201-00 |
filingDate | 1985-12-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1f04d1c77694d85d6e27108e55df6310 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_a3d05739f2ba4e75347fbf760f56b648 |
publicationDate | 1987-06-11-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | JP-S62129253-A |
titleOfInvention | Optically active alpha-dinitrophenylpropionic acid |
abstract | NEW MATERIAL:A compound expressed by the formula (* is asymmetric carbon; R is alkyl, aryl or heterocyclic ring). n EXAMPLE: S(+)-α-(2,4-Dinitrophenyl)propionic acid. n USE: A synthetic intermediate for medicines and agricultural chemicals useful also as an optical resolving agent for various amines from racemic modifications thereof. n PREPARATION: α-Phenylpropionic acid is reacted with nitric acid, preferably fuming nitric acid in the presence of sulfuric acid at 20W80°C to afford the aimed compound expressed by the formula. The nitric acid to be used for nitration is used in a slight excess of 2 equivalents, preferably 2.3W2.7 equivalents based on the α-phenylpropionic acid. The compound expressed by the formula is readily obtained by nitrating optically active α-phenylpropionic acid, derived from optically active lactic acid and obtained by a fermentation method according to this invention. n COPYRIGHT: (C)1987,JPO&Japio |
priorityDate | 1985-12-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 30.