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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B41M5-145
filingDate 1985-11-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1987-06-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S62121769-A
titleOfInvention Fluoran derivative, production thereof and recording material containing the same
abstract NEW MATERIAL:Fluoran derivatives of formula I (wherein R is CH 3 , C 2 H 5 ). n EXAMPLE: 3-(N-methyl-N-cyclohexylamino)-6-methyl-7-anilinofluoran derivative of formula II. n USE: Fluoran derivatives are heat-sensitive color forming components useful as a color forming component for thermal recording materials having excellent fastness to plasticizers, oils, org. solvents, etc. n PREPARATION: 2mol of a compd. of formula III is reacted with 1mol of a ketone of formula IV (wherein R is as defined above) in the presence of a condensing agent such as sulfuric acid, etc. and a catalyst such as FeCl 3 , etc. at 30W80°C in the presence or absence of a polar solvent such as acetonitrile for 5W60hr. The reaction product is introduced into ice/water and neutralized. The resulting precipitate is recovered by filtration, dissolved in benzene, washed with an aq. soln. of 2% NaOH, concentrated and recrystallized from an org. solvent such as toluene, etc. to obtain a fluoran derivative in a high purity. n COPYRIGHT: (C)1987,JPO&Japio
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