http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-S62119230-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_630b360599ea5cf4b5bcbc0c6c0a3e2d |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G67-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G75-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G75-029 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G75-02 |
filingDate | 1985-11-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d1fb653ee998c5ec34aaf369b680c958 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b3e4e6786ff74ab9b6bf801a9cb7fc40 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_29eb2e3deabec292e2c73e1435b5a8d6 |
publicationDate | 1987-05-30-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | JP-S62119230-A |
titleOfInvention | Production of aromatic poly(thio)ether ketone |
abstract | PURPOSE: To obtain the titled polymer having high polymerization degree under a mild condition, by reacting an aromatic (thio)ether with phosgene in the presence of a Lewis acid in an aprotic organic solvent in such a way that chemical shift of phosgene is carried out under a specific condition. n CONSTITUTION: (A) An aromatic (thio)ether (e.g., diphenylether, etc.,) shown by the formula (R 1 WR 12 are H, halogen, hydrocarbon, etc.,; X is direct bond, O or S; l is 0W5) are dissolved in 1W500pts.wt. based on the ether of (B) an aprotic organic solvent (e.g., methylene chloride, etc.,), then blended with 0.01W100mol based on 1mol component A of (C) a Lewis acid (e.g., aluminum chloride, etc.,) and (D) phosgene is introduced to the mixture preferably at ≤-10°C. In the operation, the reaction is carried out in a condition wherein difference (δ 2 -δ 1 ) (δ 2 is value when components B, C and D are mixed; δ 1 is value when components B and D are mixed) of chemical shift of two kinds of 13 C-NMR of phosgene is 6W20ppm, to give the aimed polymer. n COPYRIGHT: (C)1987,JPO&Japio |
priorityDate | 1985-11-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 31.