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filingDate 1985-06-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_c032acc4be4f70cd569f8b675583a7c8
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4a66c7a01c2fdd17799cd073db55389e
publicationDate 1986-12-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S61287964-A
titleOfInvention Production of t-butyl-substituted phthalocyanine and its intermediate
abstract PURPOSE: To obtain the titled cyanine under mild conditions with less synthetic steps by starting with inexpensive starting materials, by reacting a specified compd. with 4-t-butyl-1,2-cyanobenzene in the presence of a strong org. base in an org. solvent. n CONSTITUTION: t-Butylbenzene is reacted with bromine in the presence of a catalyst. The resulting 4-t-butyl-1,2-dibromobenzene is reacted with a metal cyanide in an org. solvent. The resulting 4-t-butyl-1,2-dicyanobenzene is reacted with a compd. of the formula MX 2 or MOR (wherein M is H, metal; X is chlorine, iodine; R is alkyl) in the presence of a strong org. base in an org. solvent to obtain the desired t-butyl-substd. phthalocyanine of the formula (wherein t-Bu is t-butyl). n COPYRIGHT: (C)1986,JPO&Japio
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http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-2007231122-A
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