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filingDate 1984-07-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_094e001461bbbe6cd20f3258e3c0975d
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_80259e154c9d9d7e6ef8ffffe6c99bc5
publicationDate 1986-02-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S6127937-A
titleOfInvention Production of beta,gamma-unsaturated aldehyde
abstract PURPOSE: To obtain the titled compound useful as an intermediate of perfumes, pharmaceuticals, agricultural chemicals, etc., in high yield, by reacting a halogen compound such as 1-bromo-3-methyl-2-butene with carbon monoxide and hydrogen in the presence of a specific palladium complex catalyst. n CONSTITUTION: The β,γ-unsaturated aldehyde (e.g. 3-pentenal) can be prepared by reacting the halogen compound of formula I (R 1 is H or methyl; R 2 is H, alkyl, alkenyl or aryl; X is halogen) (e.g. 1-chloro-2-butene) with carbon monoxide and hydrogen in the presence of a palladium complex catalyst of formula II(X' is halogen; R 3 is alkyl or aryl) [e.g. dibromobis(triphenylphosphine)palladium, etc.]. n USE: Raw material or intermediate for polymeric compounds. n COPYRIGHT: (C)1986,JPO&Japio
priorityDate 1984-07-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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