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filingDate 1985-05-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4d8730a524133e100fd973abb0420230
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publicationDate 1986-11-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S61258802-A
titleOfInvention Photopolymerizable composition
abstract PURPOSE:To provide the titled composition free from change in coloring and color tone with time, capable of giving products of good mechanical properties, e.g., printing material, dental filler, comprising a vinyl monomer and photopolymerization initiator consisting of a combination of mercaptocarboxylic acid and alpha-diketone. CONSTITUTION:The objective composition comprising (A) a vinyl monomer (e.g., ethylene glycol diacrylate, bisphenol A diglycidyl acrylate) and (B) normally 0.1-5wt%, based on said monomer, of, as a photopolymerization initiator, a combination of (i) mercaptocarboxylic acid [pref. a compound of formula I or II (R1 and R2 are each 1-5C alkylene or phenylene; R3 is NO2, OH, NH2 or halogen), e.g., o-mercaptobenzoic acid] and (ii) 0.1-20wt%, based on the component (i), of alpha-diketone (e.g., camphorquinone). EFFECT:Because of using such an initiator as to induce curing under the visible ray range, this composition will pose no health hazards; furthermore, the plant investment being inexpensive.
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