http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-S61257933-A

Outgoing Links

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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C35-08
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filingDate 1985-05-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_0263cee5b0fef15ec8f2f81b8565646b
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publicationDate 1986-11-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S61257933-A
titleOfInvention Production of stereoselective alcohol from ketone
abstract PURPOSE: To obtain an equatorial alcohol useful mainly as drugs, agricultural chemicals, etc., in the field of so-called fine chemistry, by treating a specific reagent with a ketone and reacting the reaction product with a carbon nucleating agent at ≤0°C. n CONSTITUTION: A compound shown by the formula I (R' is alkyl or halogen; R" is alkyl or H) as a reagent is treated with a ketone. Then, the reaction product is reacted with a carbon nucleating agent, preferably an organolithium compound, and/or a Grignard reagent, at ≤0°C to give the titled compound. Cyclohexane or 4-tertiary butylcyclohexane is used as the ketone. Preferably the reaction is carried out in the presence of an organic solvent at the reaction temperature of -78°C. n COPYRIGHT: (C)1986,JPO&Japio
priorityDate 1985-05-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 25.