| abstract |
PURPOSE: To obtain a π-conjugated system high polymer material having improved stereoregularity, by forming an inclusion compound wherein a monomer as a guest material is taken in a canal made of a host material and polymerizing the monomer in the canal. n CONSTITUTION: A monomer (e.g., acetylenic monomer, diacetylenic monomer, vinyl monomer such as α-chloroacrylonitrile, etc., or diene monomer) as a guest material is taken in a canal(tunnel-like space) made of a host material such as deoxycholic acid, apocholic acid, etc., to form an inclusion compound, the monomer is subjected to inclusion polymerization in the canal to give a polymer inclusion compound, and further 1,2-elimination reaction is carried out depending upon a monomer molecule. n COPYRIGHT: (C)1986,JPO&Japio |