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filingDate 1983-11-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_bad7a51e72e2d1fe41c383d4b3a016ec
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publicationDate 1985-05-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S6097922-A
titleOfInvention Preparation of styrene and/or ethylbenzene by alkylation of side chain of toluene
abstract PURPOSE: To obtain the titled compound economically by one process without using benzene as a starting raw material and without causing disadvantages such as corrosion of device, by subjecting inexpensive toluene as a starting raw material to side chain alkylation in the presence of an alkylating agent in a gaseous phase under specific conditions. n CONSTITUTION: Toluene as a raw material is catalytically subjected to side chain alkylation in a gaseous phase in the presence of an alkylating agent at 0.01W0.8, preferably 0.1W0.8 atmospheric pressure of reaction pressure measured as absolute pressure at 2W10ml/ml-catalyst-hour, to give styrene and/or ethylbenzene. One or more of methanol, formaldehyde, methylal, etc. are used as the alkylating agent, and especially methanol is preferable. A molar ratio of methanol/toluene as the raw materials is preferably (1/2)W(1/20), more preferably (1/3)W(1/10). n COPYRIGHT: (C)1985,JPO&Japio
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