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filingDate 1983-07-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_0d33ca652435312e2d5d29f4c5ce6e25
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publicationDate 1985-02-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S6028938-A
titleOfInvention Preparation of nitrile by nitroxidation
abstract PURPOSE: To obtain a nitrile in high selectivity, by subjecting a gaseous mixture of an organic compound containing a methyl group directly linked to a (hetero) aromatic ring or methyl group directly linked to C=C bond and NO to contact reaction in a catalyst of zinc oxide. n CONSTITUTION: A gaseous mixture of a compound [e.g., compound shown by the formula I (R 1 is 1W4C alkyl, alkoxy, or halogen; m is 0, or 1] containing CH 3 directly linked to an aromatic ring, a compound (e.g., compound shown by the formula II) containing CH 3 directly linked to a hetero aromatic ring, or a compound [e.g., compound shown by the formula III (R 2 is H, or CH 3 )] directly linked to C=C bond and NO is subjected to contact reaction on a catalyst of zinc oxide or zinc oxide supported on a carrier (e.g., silica, or magnesia) at 350W600°C, to give a corresponding nitrile. The catalyst is prepared by dispersing a carrier into zinc nitrate, zinc salt of organic carboxylate, etc. or an aqueous solution containing it, neutralizing it with an alkali to give precipitate, calcining the precipitate at 400W1,000°C. n COPYRIGHT: (C)1985,JPO&Japio
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