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filingDate 1984-05-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2ec638a4d886448dbed058935e1f0b63
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publicationDate 1985-12-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S60243031-A
titleOfInvention Production of isoprene
abstract PURPOSE: To produce isoprene from an isobutylene source and a formaldehyde source, economically, under specific condition, by using inexpensive spent BB fraction as the isobutylene source, and subjecting the source to the low-temperature reaction step, 4C compound removal step, high-temperature reaction step and purification step. n CONSTITUTION: An isobutylene source is made to react with a formaldehyde source continuously in a liquid phase in the presence of an acidic catalyst and water to obtain isoprene. In the above process, the butane-butene fraction containing isobutylene and produced as a by-product of the catalytic cracking of petroleum is used as the isobutylene source, and is subjected to (1) the low-temperature reaction step 4 comprising the synthesis of isoprene precursor by reacting with a formaldehyde source at 50W140°C, (2) the 4C compound removal step 13 to remove the 4C hydrocarbon from the liquid obtained by the step (1), (3) the high-temperature reaction step 16 to decompose the isoprene precursor in the liquid obtained by the step (2) to isoprene at 145W230°C, and (4) the purification step 23 to purify the produced isoprene. Isoprene can be produced efficiently from an inexpensive raw material with a simple apparatus. n COPYRIGHT: (C)1985,JPO&Japio
priorityDate 1984-05-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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