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filingDate 1984-03-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1985-10-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S60193970-A
titleOfInvention Thiocyanopyrimidine derivative, its preparation and fungicide for agricultural and horticultural purposes
abstract NEW MATERIAL:A thiocyanopyridine derivative of formula I [R is -SR 1 (R 1 is 1W3C alkyl), 1W4C alkyl, allyl, propargyl, benzyl; X is halogen]. n EXAMPLE: 2,4-Dichloro-5-methylthio-6-thiocyanopyrimidine. n USE: A fungicide for agricultural and horticultural purposes. It shows very excellent effect against plant disease-causative fungi such as apple Alternaria blotch, potato late blight, cucumber gray mold and downy mildew without adverse effect on the crops such as tomatos, cucumbers and potatos, further with low toxicity to animals. n PREPARATION: The reaction between a pyrimidine derivative of formula II and a thiocyanate salt of the formula: M-SCN (M is alkali metal) such as KSCN is carried out in formic acid at 20W60°C for less than 1hr to give the compound of formula I in yield of more than 90%. n COPYRIGHT: (C)1985,JPO&Japio
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