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filingDate 1982-10-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1984-04-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S5965064-A
titleOfInvention Preparation of 1,4-diamino-2,3-dicyanoanthraquinone
abstract PURPOSE: To prepare the titled compound economically in an industrial scale, by reacting 1,4-diamino-2,3-dihalogenoanthraquinone with a sulfonating agent in an aqueous medium in the presence of a quaternary ammonium compound, and reacting the product with a cyanizing agent without separating from the reaction system. n CONSTITUTION: 1,4-Diamino-2,3-dihalogenoanthraquinone is made to react with a sulfonating agent such as sodium sulfite in an aqueous medium in the presence or absence of an inert organic solvent, in the presence of a quaternary ammonium compound of formula I (R 1 and R 2 are 1W24C alkyl, etc.; R 3 and R 4 are 1W10C alkyl; X is anion residue) or formula II (R 5 is 1W24C alkyl; R 6 is H or methyl) and/or a quaternary phosphonium compound of formula III (R 7 W R 10 are 1W24C alkyl, etc.) to obtain 1,4-diaminoanthraquinone-2,3-disulfonic acid or its salt. Without separating the product from the reaction system, the compound is made to react with a cyanizing agent such as sodium cyanide to obtain the objective compound. n COPYRIGHT: (C)1984,JPO&Japio
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