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filingDate 1980-06-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_23f3733f2610cffd0840ec07439f6b71
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publicationDate 1982-01-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S579762-A
titleOfInvention Production of trifluoromethylpyridine
abstract PURPOSE: The gas-phase reaction between α-picoline, γ-picoline or lutidine, chlorine and anhydrous hydrogen fluoride is effected using a catalyst of a fluoride of Al, Cr, Fe and a diluent to produce the titled compound in a single stage in a short time. n CONSTITUTION: The gas-phase reaction between α-picoline, γ-picoline or lutidiene, chlorine and anhydrous hidrogen fluoride is conducted in the presence of a catalyst consisting of a fluoride of metallic atom such as Al, Cr, Fe, Ni, Mn or co, e.g., AlF 3 , CrF 2 , FeF 2 and a diluent such as carbon tetrachloride or chloroform to produce a trifluoromethylpyridine such as α-trifluoromethylpyridine, γ-trifluoromethylpyridine, bistrifluoromethylpyridine or a trifluoromethylpyridine derived from a pyridine substituted with chlorine atoms on the nucelus carbons. It can be purified by a usual procedure to give high-purity and isomer free compounds. n USE: Raw material for herbicide and insecticide. n COPYRIGHT: (C)1982,JPO&Japio
priorityDate 1980-06-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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