http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-S5748932-A

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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C49-227
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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C49-84
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filingDate 1980-09-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_080bf8b11b8081a1df2da5aad62073ed
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d0060e6aeeed4c5d5fce8ba24bc9fba9
publicationDate 1982-03-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S5748932-A
titleOfInvention Gamma,delta-unsaturated alpha,alpha-dichlorocarbonyl compound and its preparation
abstract NEW MATERIAL:The compound of formula I (R 1 is H, alkyl, alkenyl or aryl; R 2 WR 4 are H or lower alkyl; provided that R 1 WR 4 are not H at the same time). n EXAMPLE: 2,2,-Dichloro-1-phenyl-4-penten-1-one. n USE: A synthetic intermediate for the preparation of useful terpene compounds. n PROCESS: The ether of a 2,2,2-trichloroethyl compound and an allyl compound (formula II) is dehydrochlorinated by reacting in the presence of a base such as potassium tert-butoxide, in a solvent such as tetrahydrofuran, for several hours with or without heating. The objective compound of formula I can be prepared, in high efficiency, by the thermal rearrangement of the resulted ether of 2,2-dichlorovinyl compound and an allyl compound (formula III) at 100W150° for about 30min. n COPYRIGHT: (C)1982,JPO&Japio
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Total number of triples: 27.