http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-S5748932-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_96c2bc15e5124eef4ea3140b451236f3 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C49-227 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C49-84 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C47-24 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C49-80 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-51 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C67-00 |
filingDate | 1980-09-08-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_080bf8b11b8081a1df2da5aad62073ed http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d0060e6aeeed4c5d5fce8ba24bc9fba9 |
publicationDate | 1982-03-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | JP-S5748932-A |
titleOfInvention | Gamma,delta-unsaturated alpha,alpha-dichlorocarbonyl compound and its preparation |
abstract | NEW MATERIAL:The compound of formula I (R 1 is H, alkyl, alkenyl or aryl; R 2 WR 4 are H or lower alkyl; provided that R 1 WR 4 are not H at the same time). n EXAMPLE: 2,2,-Dichloro-1-phenyl-4-penten-1-one. n USE: A synthetic intermediate for the preparation of useful terpene compounds. n PROCESS: The ether of a 2,2,2-trichloroethyl compound and an allyl compound (formula II) is dehydrochlorinated by reacting in the presence of a base such as potassium tert-butoxide, in a solvent such as tetrahydrofuran, for several hours with or without heating. The objective compound of formula I can be prepared, in high efficiency, by the thermal rearrangement of the resulted ether of 2,2-dichlorovinyl compound and an allyl compound (formula III) at 100W150° for about 30min. n COPYRIGHT: (C)1982,JPO&Japio |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-S62196672-U http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-H0339037-Y2 |
priorityDate | 1980-09-08-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 27.