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filingDate 1980-09-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_a30cc0eef7c5df46e3ac5d9571938c13
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publicationDate 1982-03-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S5746933-A
titleOfInvention Preparation of 1-alkoxy-2-propanone
abstract PURPOSE: To prepare the titled substance useful as an organic synthetic intermediate, in high yield and selectivity under mild conditions, by isomerizing glycidyl ether with a catalyst comprising a 8-group transition metal carbonyl complex. n CONSTITUTION: The compound of formula II is prepared by contacting the glycidyl ether of formula I (R is primary, secondary or tertiary, straight or branched, saturated or unsaturated alkyl, saturated or unsaturated cycloalkyl, or aralkyl) with a 8-group transition metal carbonyl complex catalyst. The catalyst is pref. a binuclear complex of a 8-group transition metal [e.g. dicobalt octacarbonyl [Co 2 (CO) 8 ]]. To produce the active species from the complex for the smooth reaction, a Lewis base (esp. alcohol) is pref. used as a solvent. The amount of the catalyst is 0.03W0.10mol/mol of the raw material. n COPYRIGHT: (C)1982,JPO&Japio
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Total number of triples: 28.