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filingDate 1980-08-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_c25440c1c5dd4b2cc880a922187f5f52
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publicationDate 1982-03-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S5738799-A
titleOfInvention 25-hydroxy-3,24-dioxocholesta-1,4,6-trienes and their preparations
abstract NEW MATERIAL:A 25-hydroxy-3,24-dioxochelesta-1,4,6-triene shown by the formula I (R is H or OH-protecting group). n EXAMPLE: 25-Acetoxy-3,24-dioxocholesta-1,4,6-triene. n USE: An intermediate for an active type vitamin D 3 (e.g, 1α,24,25-trihydroxy VD 3 or 1α, 25-dihydroxy-24-oxo VD 3 ). n PROCESS: A 3α-25-dihydroxy-24-oxocholesto-5-ene shown by the formula II is reacted with 2,3-dichloro-5,6-dicyanobenzoquinone in an inert solvent(e.g., hexane, THF, etc.), and, if necessary, the protecting group(e.g., acyl) is removed to give a compound shown by the formula I. The reaction is carried out using 2,3-dichloro-5,6- dicyanobenzoquinone in an amount 1W10 times as much as the equivalent of the compound shown by the formula II at 70W200°C for 1W50 hours. n COPYRIGHT: (C)1982,JPO&Japio
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priorityDate 1980-08-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 33.