http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-S572272-A

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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D209-52
filingDate 1980-06-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_00645b5174c568b85825368f282feede
publicationDate 1982-01-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S572272-A
titleOfInvention Preparation of n-phenylcyclopropanedicarboxylic acid imide derivative
abstract PURPOSE: To prepare the titled compound useful as a nonmedical fungicide, in high purity, by hydrolyzing 2-dimethylcyclopropanedicarboxylic acid di-(lower alkyl) ester with heating in the presence of 3,5-dihalogennaniline under acidic conditions. n CONSTITUTION: In the preparation of an N-phenylcyclopropanedicarboxylic acid imide derivative of formula II by the hydrolysis of 1,2-dimethylcyclopropanedicarboxylic acid di-(lower alkyl) ester of formula I (R 1 and R 2 are lower alkyl) under acidic conditions in water, the hydrolysis is carried out by heating at 85W120°C, pref. 90°CW the boiling point of the reaction mixture, in the presence of 3,5-dihalogenoaniline (e.g. 3,5-dichloroaniline). The raw material is a mixture of cis- and trans-isomers. Only the cis isomer is imidized, and the trans-isomer can be removed as the aqueous solution. n COPYRIGHT: (C)1982,JPO&Japio
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priorityDate 1980-06-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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