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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-95
filingDate 1981-05-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_bd1da550bcb9a6f47afc29d9b11dd334
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publicationDate 1982-11-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S57185237-A
titleOfInvention Preparation of 2,5-dihalo-1,4-benzoquinone-3,6-dicarboxylic diester
abstract PURPOSE: To obtain the titled compound in high yield and purity without taking out an intermediate product, by halogenating and oxidizing any 2,5-dialkoxycarbonyl-1,4-cyclohexanedione in a nonpolar inert organic solvent continuously. n CONSTITUTION: A 2, 5-dialkoxycarbonyl-1, 4-cyclohexanedione, e.g. 2, 5-diethoxycarbonyl-1,4-cyclohexanedione, of formulaI (R is 1W12C alkyl) is continuously halogenated and oxidized with a halogen, e.g. bromine, in a nonpolar inert organic solvent, e.g. dichloromethane, chloroform or carbon tetrachloride, to give the aimed compound of formula II (X is halogen) without taking out the 1, 4- hydroquinone derivative formed as an intermediate. n EFFECT: Easily preparable in a short time. n USE: Organic oxidizing agents, intermediates for various important compounds, etc. n COPYRIGHT: (C)1982,JPO&Japio
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4735744-A
priorityDate 1981-05-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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