http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-S57139099-A

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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07J7-00
filingDate 1981-02-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_932d251d76dba73f2f7d4d1810c7f646
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publicationDate 1982-08-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S57139099-A
titleOfInvention Preparation of intermediate for preparing corticoid
abstract PURPOSE: To obtain an adrenocortical hormone in short steps, by reacting a novel 17β-ethynylsteroid obtained from androsta-4,9(11)-diene-3,17-dione, etc. with water in the presence of a mercury compound. n CONSTITUTION: A novel 17β-ethynylsteroid, e.g. 17β-ethynyl-17α-hydroxyandrosta- 1,4-dien-3-one, etc. of formulaI(the dotted line is single or double bond), obtained from androsta-4,9(11)-diene-3,17-dione easily derived from 9α-hydroxyandrost-4- ene-3,17-dione as a raw material is reacted with water in the presence of a mercury compound, e.g. mercuric chloride or mercuric oxide, in a molar amount of preferably 0.5W5 times that of the ethynylsteroid, at preferably 30W70°C to give the aimed compound of formula II. n COPYRIGHT: (C)1982,JPO&Japio
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-109438540-A
priorityDate 1981-02-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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