http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-S56120637-A

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filingDate 1981-02-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_26b5c04db6950ca75f2b171a812ca260
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publicationDate 1981-09-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S56120637-A
titleOfInvention Preparation of high-purity terephthalic acid
abstract PURPOSE: To obtain high-purity terephthalic acid for direct polymerization, by the oxidation of p-tolualdehyde with molecular oxygen, in the presence of water and Mn, Ce, a bromine compound and a mineral acid in a specific proportional as a catalyst. n CONSTITUTION: p-Tolualdehyde is oxidized with molecular oxygen in the presence of water as a solvent, heavy metallic catalysts and a bromine compound. As the heavy metallic catalysts, Mn and Ce are used and the bromine compound is maintained at 0.5W12wt% based on the reaction solution as bromide ions, and the g- equivalent of the hydrogen ions of the mineral acid is maintained at 1W85% based on the total g-equivalent of hydrogen, Mn and Ce ions, and the total g-equivalent of hydrogen ions, Mn and Ce is maintained at 0.5W5 times that of g-equivalent of bormine ions. n COPYRIGHT: (C)1981,JPO&Japio
priorityDate 1981-02-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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