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filingDate 1980-02-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_0af06ed0b8002162f4a6e8e7be49b05d
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publicationDate 1981-09-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S56116708-A
titleOfInvention Preparation of polybutadiene
abstract PURPOSE: To prepare a polybutadiene contg. high-melting 1,2-polyburadiene, by the polymn. of 1,3-butadiene in the presence of a specified catalyst. n CONSTITUTION: 1,3-Butadiene is polymerized in the presence of a catalyst consisting of (A) 1mol of a solvent-sol. Co cpd. (e.g., cobalt naphthenate), (B) 1W500mol of a dialkylaluminum halide or a mixt. with a trialkylaluminum contg. 90mol% or more dialkylaluminum halide and (C) 0.005W100mol of CS 2 or phenyl isothiocyanate, in a polymn. solvent, in an inert gas atmosphere at -20W80°C, to obtain a polybutadiene contg. 5W80% syndiotactic 1,2-structure, 10W90% cis-1,4 structure and the balance of atactic 1,2-structure. n COPYRIGHT: (C)1981,JPO&Japio
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type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 25.