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filingDate 1979-04-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_e98c6a48a2d64b84052c69d2271484e9
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publicationDate 1980-10-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S55137117-A
titleOfInvention Curable unsaturated resin, production thereof, and curable composition containing the same
abstract PURPOSE: To obtain an unsaturated resin having excellent surface hardening properties and adhesive properties of cured film to a substrate, by a method wherein a reaction product of rosin and an α,β-ethylenically unsaturated dicarboxylic acid is reacted with a polyhydric alcohol and glycidyl (meth)acrylate. n CONSTITUTION: A reaction product of rosin and an α,β-ethylenically unsaturated dicarboxylic acid and/or anhydride thereof is reacted with a polyhydric alcohol and glycidyl acrylate and/or glycidyl methacrylate in an inert solvent with heating in the presence of a thermal polymn. inhibitor and an esterification catalyst. When the reaction temp. exceeds 150°C, there is a tendency to form gel. At a low temp. below 50°C, the reaction rate is slow. It is preferred to carry out thereaction at a temp. of 50W150°C. Examples of the thermal polymn. inhibitors are phenothiazine and benzoquinone. n COPYRIGHT: (C)1980,JPO&Japio
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