http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-S55108832-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_d9cb217f83556ce2a418344c2d485415 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C207-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-51 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C201-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C49-403 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C67-00 |
filingDate | 1979-02-14-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_5d22841bed3329f1ab0b8d9a1113b76e http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_bd8b9727279675860671ab4c529d04d8 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_898d09899231c5b7c9ac4ea59994860d |
publicationDate | 1980-08-21-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | JP-S55108832-A |
titleOfInvention | Preparation of nitrosocyclohexane dimer and cyclohexanone |
abstract | PURPOSE: To obtain nitrosocyclohexane dimer, which is an important starting material of polycaprolactam, and cyclohexanone simultaneously, by the thermal decomposition of 1-dicyclohexyl nitrite. n CONSTITUTION: The thermal decomposition of 1-dicyclohexyl nitrite gives nitrosocyclohexane dimer and cyclohexanone. 1-Dicyclohexyl nitrite is obtained for example, as follows: benzene is hydrogenated and dimerized to give cyclohexylbenzene, which is then oxidized to afford 1-hydroxycyclohexylbenzene: The hydrogenation of 1-hydroxycyclohexylbenzene thus obtained gives 1-dicyclohexanol, which is made to react with nitrosyl chloride or dinitrogen trioxide to give the objective 1- dicyclohexyl nitrite. Addition of an inert gas, e.g. nitrogen monoxide, argon etc., or an inert organic solvent as a diluent to the thermal decomposition system improves the selectivity of the objective compound. n COPYRIGHT: (C)1980,JPO&Japio |
priorityDate | 1979-02-14-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 38.