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publicationDate 1998-03-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H1072389-A
titleOfInvention Method for producing methacrolein and methacrylic acid
abstract (57) [Summary] (Modifications) [PROBLEMS] To produce methacrolein and methacrylic acid by subjecting isobutylene to gas-phase catalytic oxidation, suppress the heat storage in the hot spot portion in the catalyst layer, improve the yield, and improve the catalyst. Prevent deterioration and use stably for a long time. SOLUTION: a) As a catalyst, a general formula (I): Mo a W b Bi c Fe d A e B f C g D h E i O x (A is at least one element of Ni and Co, B is one or more elements of the alkali metal and Tl, C is the alkaline earth metal 1 The above elements of the species, D is P, Te, Sb, Sn, Ce, Pb, Nb, Mn, As And one or more elements of Zn, E represents one or more elements from Si, Al, Ti and Zr, a, b, c, d, e, f, g, h, i and x are b = 0 to 10, c = 0.1 to 10, and d = 0.1 to 2 when a = 12. 0, e = 2 to 20, f = 0 to 10, g = 0.001 to 1 0, h = 0 to 4, i = 0 to 30, x = a value determined by the oxidation state of each element), and b) the catalyst layer in each reaction tube is formed into two or more layers in the tube axis direction. C) a plurality of catalysts having different activities, prepared by changing the type and / or amount of the group C element of the catalyst of the general formula I, into a plurality of reaction zones provided separately, from the inlet to the outlet of the raw material gas; Filling to increase the activity toward.
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