| abstract |
(57) [Abstract] [Purpose] Providing a method with a high addition rate of an epoxy compound to an alcohol [Structure] A method for producing an adduct by reacting an alcohol with an epoxy compound, which is represented by the formula I: ] (In the formula, A represents an aliphatic group and r represents a number of 1 to 10.) Of the alcohol of formula II as a catalyst with a mono- or diepoxide in an equivalent ratio of 1:20 to 20: 1 based on the hydroxyl and epoxy groups: (In the formula, M is, for example, La, Cu, Zn or Fe, L 1 and L 2 are benzyl phenyl sulfide, CH 3 CN or H 2 O, and L 3 is a strong-bonding non-substituted neutral. Or anion single- The multidentate ligand, X is BF 4 -, ClO 4 - or CF 3 SO 3 -, and k is 1 or 2, x is 1-1000, y is 0-1000, and z is Represents 0-6. Method of reacting in the presence of a metal complex). |