| abstract |
(57) [Summary] [Objective] An olefin oxide or hydrogenated product is obtained by reacting an olefin with oxygen or hydrogen under mild conditions using a catalyst. [Structure] A catalyst comprising a platinum complex represented by the following formula (1), (2), (3) or (4) or a salt thereof. [Pt 4 (NH 3 ) 8 (L) 4] n + ... (1) [Pt 8 (NH 3 ) 16 (L) 8 ] m + ... (2) [Pt 2 (NH 3 ) 4 (L ) 2 ] 2 + ... (3) [Pt 2 (NH 3 ) 4 (L) 2 (L ′) (L ″)] l + ... (4) (In the formula, L is a deprotonated amide compound. Each of the ligands, L ′ and L ″ represents a ligand, n is 5 or 6, m is 9 or 10, and l is 0, 2, 3 or 4. Here, platinum complexes (1) to (4) or a salt thereof, L is C 5 H 10 NO Alternatively, those which are C 7 H 6 NO are novel compounds. |