| abstract |
(57) [Summary] (Modified) [Objective] A method for obtaining an amino group-containing compound such as an optically active dipeptide or an optically active amino acid from an oxime compound by a novel reaction. A method for producing an amino group-containing compound of general formula (c), which comprises a step of reacting an oxime compound of general formula (a) in the presence of samarium iodide S m I 2 and an alcohol of general formula (b) Method. [R 1 and R 2 may be the same or different and each is a hydrogen atom, a linear or branched alkyl group or an aryl group, and may have a substituent, and R 3 is a hydrogen atom, a linear or branched group. Alkyl group or aryl group, which may have a substituent, R 4 and R 5 may be the same or different, and are a hydrogen atom, a linear or branched alkyl group or aryl group, and R 1 and R 2 or R 4 and R 5 may be bonded to each other to form a ring. ROH (b) [R is a hydrocarbon group] |