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filingDate 1991-10-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1993-04-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H05100084-A
titleOfInvention Oxidation method of trivalent plutonium to tetravalent plutonium
abstract (57) [Summary] (Modified) [Purpose] Pu reoxidation step and Pu of Purex process for recovering U and Pu in spent nuclear fuel In the concentration step, a nitric acid solution containing Pu 3+ , hydroxylamine nitrate as a reducing agent and hydrazine as a stabilizer is oxidized to oxidize Pu 3+ to Pu 4+, and at the same time, remove hydroxylamine nitrate and hydrazine. An oxidation / decomposition method for decomposing is provided. [Constitution] A nitric acid solution containing Pu 3+ , hydroxylamine nitrate and hydrazine is electrolytically oxidized. This makes Pu 3+ is almost completely oxidized to Pu 4+ , and hydroxylamine nitrate and hydrazine are finally almost completely decomposed into nitrogen gas and hydrogen gas. Hydroxylamine nitrate as the reducing agent, although the nitric acid solution in which Pu 3+ is absent is electrochemically very stable, since this the Pu 3+ is present acts as a catalyst in the electrode reaction system efficiently by electrolytic It can be disassembled.
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http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-114570289-A
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