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filingDate 1990-08-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_bfea730a1d6bfc6d22dd6a311a99d821
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publicationDate 1992-06-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H04159288-A
titleOfInvention Optically active phosphine compound
abstract NEW MATERIAL: A compound of formula I (R 1 is morpholino: R 2 is H). n USE: A synthetic intermediate for a new optically active metal coordination complex catalyst useful in catalytic hydrogenation of olefinic compounds. The catalyst is usable in an aqueous medium and are capable of performing asymmetric hydrogenations efficiently and rapidly. n PROCESS: CH 3 SO 2 Cl is reacted with a compound of formula II to form morpolinomethyl sulfonamide of formula III. The product is reacted with (S)-p- methyl-o-methoxyphenyl-methyl phosphinate of formula IV in THF in the presence of n-butyl lithium. n COPYRIGHT: (C)1992,JPO
priorityDate 1980-12-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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