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filingDate 1990-05-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ddcbe4dc8b3ad469a36c848c40fe5ca3
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publicationDate 1992-01-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H0413643-A
titleOfInvention Production of chloroacetals
abstract PURPOSE: To obtain acyclic or cyclic chloroacetals in high purity independent of production of raw materials by reacting a monochloracetoaldehyde trimer with a 1-5C mono- or dihydric alcohol in the presence of an acid catalyst or a dehydrating agent. n CONSTITUTION: A monochloroacetaldehyde(MCA) monomer is reacted with a 1-5C mono- or dihydric alcohol in the presence of an acid catalyst, e.g. p- toluenesulfonic acid or dilute sulfuric acid or a dehydrating agent such as anhydrous calcium chloride at ≥120°C, preferably 130-160°C temperature under ordinary or higher pressure. Thereby, MCA trimer capable of stably existing for a long period is used as a raw material for acetalization to industrially and advantageously provide acyclic or cyclic chloroacetals useful as a raw material for medicines or polymer compounds in high purity. Furthermore, the MCA trimer may be heated in the presence of the acid catalyst to afford a monomer, which is then reacted with the aforementioned alcohol. n COPYRIGHT: (C)1992,JPO&Japio
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