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filingDate 1990-09-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_bfc719c499973978b453931a679f1202
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publicationDate 1992-05-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H04134058-A
titleOfInvention Production of aromatic urea compound
abstract PURPOSE: To obtain the title compound safely, readily and in high yield without requiring facilities for high pressure by reacting an aromatic amine with an N-formyl aromatic amine compound in the presence of a catalyst consisting essentially of a compound containing a platinum group under a mild condition. n CONSTITUTION: An aromatic amine such as aniline shown by formula I (R 1 is H, Cl, CH 3 , OCH 3 , etc.) is reacted with an N-formyl aromatic amine compound such as formanilide shown by formula II (R 2 =R 1 ) preferably in a solvent such as mesitylene in the presence of a compound such as an organometallic compound, e.g. RuCl 2 (PPh 3 ) 3 (PPh 3 is triphenylphosphine) containing a platinum group metal and a ligand such as CO or phosphine or an organic group at 30-300°C preferably 120-200°C under normal pressure for several minutes to several hours to give the objective compound such as N,N'-diphenlurea shown by formula III useful as an intermediate for producing herbicides, plant growth regulators and urethane. The above-mentioned method has a minimum cost of facilities. n COPYRIGHT: (C)1992,JPO&Japio
priorityDate 1990-09-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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