http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-H0395189-A

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filingDate 1989-09-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_788297d2d5a2dab6c3101bd7f32882f0
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publicationDate 1991-04-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H0395189-A
titleOfInvention Optically active alcohol and its production
abstract NEW MATERIAL:The compound of formula I or II [R 1 to R 3 are 1-10C alkyl; R 4 and R 5 are 1-10C (substituted) alkyl or (substituted) phenyl and are different from each other] having silyl group at γ-site. n EXAMPLE: The epoxy alcohol of formula III. n USE: A synthetic intermediate for pharmaceuticals and agricultural chemicals such as prostaglandin. n PREPARATION: An epoxyketone compound having silyl group at γ-site and expressed by formula IV or V is made to react with preferably 0.8-1.5 equivalent of an organic magnesium reagent of formula R 5 MgX (x is Cl, Br or I) (e.g. CH 3 MgI or C 2 H 5 MgBr) at -78 to 0°C for 0.5-5hr. n COPYRIGHT: (C)1991,JPO&Japio
priorityDate 1989-09-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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Total number of triples: 25.