http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-H0393749-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_6cfc033f059d282fcd915bc8be2ae53f |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C211-49 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C209-24 |
filingDate | 1989-09-05-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6642359c2d095cdd88d4d5b9d5566843 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_c70c8fcdbe3bf31d144288539a866cbd http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_e693e771288d3d521b9e75193e94f57a http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2518660160bd72b590ad74f3d94729bc |
publicationDate | 1991-04-18-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | JP-H0393749-A |
titleOfInvention | Production of alpha-(3-aminophenyl)ethylamine |
abstract | PURPOSE: To obtain the subject compound such as a polymer curing agent in high selectivity by carrying out two-state reaction of m-nitroacetophenone through m-aminoacetophenone in the same solvent using a specific catalyst and additive. n CONSTITUTION: m-Nitroacetophenon expressed by formula I is catalytically reduced with hydrogen in the presence of a catalyst and a solvent to provide m-aminoacetophenon expressed by formula II. The solvent is then directly used to aminate the resultant compound with hydrogen and ammonia in the presence of a catalyst, a small amount of a weak acid or ammonium salt of the weak acid and afford α-(3-aminophenyl)ethylamine expressed by formula III. The aforementioned method can be advantageously carried out under conditions of a low temperature under a low pressure and the small amount of the weak acid or ammonium salt thereof can be added to suppress side reaction. The m-aminoacetophenone expressed by formula II may be obtained by taking out part or the total amount of the reaction product in the intermediate stage of the above-mentioned reaction and carrying out simple purification. n COPYRIGHT: (C)1991,JPO&Japio |
priorityDate | 1989-09-05-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 29.