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filingDate 1989-08-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2c7fda42cda47972e8f0a03d52788802
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publicationDate 1991-03-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H0374368-A
titleOfInvention New azole-substituted cycloalkanol derivative, preparation thereof and agricultural and horticultural antimicrobial agent containing the same derivative
abstract NEW MATERIAL:A compound of formula I (R 1 is lower alkyl; R 2 is H or lower alkyl; n is 1 or 2; A is N or CH). n EXAMPLE: 2-(4-Chlorobenzyl)-7-ethyl-1-(1H-1,2,4-triazol-1-ylmethyl)-1-cycloheptanol. n USE: A low toxic agricultural or horticultural antimicrobial agent exhibiting excellent controlling activity against broad plant diseases and having high safety on the handling thereof. n PREPARATION: A new compound of formula V prepared from 1-(4- chlorobenzyl)-2-oxocycloalkanecarboxylic acid alkyl ester through a new compound of formula II or new compounds of formulas III and IV is subjected to an oxirane reaction using a sulfonium methylide or sulfoxonium methylide, or a new compound of formula VI prepared form the new compound of formula V by a Witting reaction is epoxidized to prepare a new compound of formula VII. The compound of formula VII is reacted with a compound of formula VIII (M is H or alkali metal) to provide the compound of formula I. n COPYRIGHT: (C)1991,JPO&Japio
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