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filingDate 1990-04-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6cd5b6abc3e4609c1779fe0626a9e779
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publicationDate 1991-12-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H03291279-A
titleOfInvention 6-epithioethyl-3-oxatricyclo(3.2.1.02,4)octane and production thereof
abstract NEW MATERIAL:A compound expressed by formula I. n USE: A raw material monomer for heat-resistant plastics and optical plastics. Since the polymer of the aforementioned compound has a bicyclo[2.2.1]heptane skeleton and contains sulfur, the polymer is amorphous with a high glass transition temperature and capable of exhibiting a high refractive index and low dispersibility. n PREPARATION: 6-Epoxyethyl-3-oxatricyclo[3.2.1.0 2 , 4 ]octane expressed by formula II is reacted with a thiocyanate expressed by the formula M(SCN) n (M is metallic ion, NH 4 or primary to quaternary ammonium ion having 1-4C alkyl; n is 1 or 2) and/or a thiourea expressed by the formula (R 2 N) 2 C=S (R is H, 1-10C alkyl or aryl) in a solvent such as THF or in the absence thereof at 0-100°C to afford the objective compound expressed by formula I. n COPYRIGHT: (C)1991,JPO&Japio
priorityDate 1990-04-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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