http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-H03247299-A
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_dae64c775f32c43199adbb4389c2c9b3 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C12P41-00 |
filingDate | 1990-02-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_180d0f33ad92bbbcd59a4f3f5decaaa4 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_e7c28d28738a15b837618239da095e33 |
publicationDate | 1991-11-05-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | JP-H03247299-A |
titleOfInvention | Optically active secondary alkyne alcohol by biochemical technique |
abstract | PURPOSE: To readily and efficiently obtain the subject compound useful as medicines, agricultural chemicals, etc., in high purity by subjecting an ester of a racemic alkyne alcohol to asymmetric hydrolytic reaction in the presence of a specific enzyme under specified pH conditions. n CONSTITUTION: An (R,S)-ester expressed by formula I (l and n are 0-4; m is 0 or 1; C* is asymmetric carbon atom) [e.g. (R,S)-3-acetoxy-1-butyne] is subjected to hydrolytic reaction in the presence of an enzyme (preferably a lipase, etc.) having the ability to react with the compound expressed by formula I and preferentially carry out asymmetric hydrolytic reaction with either of the R- and S-isomers at pH≥3 and resolved into an optically active alcohol, expressed by formula II and rich in either of the R- and S-isomers. n COPYRIGHT: (C)1991,JPO&Japio |
priorityDate | 1990-02-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 57.