http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-H03176449-A

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classificationCPCAdditional http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y02P20-55
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C309-73
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filingDate 1989-12-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_a9ee13ea69c24055eb578d93245d205e
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d7c6a9e18782075fe3e744288f00dbc2
publicationDate 1991-07-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H03176449-A
titleOfInvention Optically active 2-methylenepentanal derivative
abstract NEW MATERIAL:An optically active compound shown by formula I (R 1 is H or readily eliminable protecting group selected from alkenyl, aralkyl, alkyloxymethyl, 1-alkyloxyethyl, hetero atom-containing cyclic alkyl and silyl; X is halogen or R 4 SO 3 ; R 4 is alkyl or aryl; * shows asymmetric carbon atom). n USE: An intermediate for producing prostaglandins by an extremely shorter process than a well-known method. n PREPARATION: A compound shown by formula II (X 1 is halogen; R 3 is readily eliminable protecting group selected from alkyl and aralkyl which may contain halogen-substituted group and two R 3 may be bonded to form cyclic acetal) is made to react with an optically active compound shown by formula III to give a compound shown by formula IV and a protecting group R 1 is introduced to OH thereof to give a compound shown by formula V. Then the acetal part of the compound shown by formula V is hydrolyzed in the presence of a weak Lewis acid to give a compound shown by formula I. n COPYRIGHT: (C)1991,JPO&Japio
priorityDate 1989-12-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 29.