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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D311-10
filingDate 1988-09-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d42a5a1f98a6147b1603a3ded9fa1a7d
publicationDate 1990-04-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H0296574-A
titleOfInvention Production of coumarin
abstract PURPOSE: To readily produce a coumarin useful as a perfume, food flavor, metal surface-treating agent for plating operations, etc., in a good yield with simple device and process by reacting dihydrocoumarin as a raw material with sulfur and a desulfurizing agent. n CONSTITUTION: Dihydrocoumarin prepared by catalytically cyclizing and dehydrogenating 3-(2-cyclohexanoyl)propionic acid or an ester thereof catalytically hydrogenating hexahydrocoumarin is reacted with preferably the same chemical amount or, if desired, a little excess amount of sulfur and subsequently with a desulfurizing agent such as Raney nickel developed in a solvent such as phenyl ether at ≥200°C, preferably 240-280°C, to provide the coumarin of formula II. n COPYRIGHT: (C)1990,JPO&Japio
priorityDate 1988-09-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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