http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-H02258733-A
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_1e70c0aeade92d7571d955d3b90ea06e |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C17-23 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C17-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C19-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C17-23 |
filingDate | 1990-01-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_036813e30af760b4c27cba42f66cce5a http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_560f2d8be151b5725aaa665ec3e31abc |
publicationDate | 1990-10-19-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | JP-H02258733-A |
titleOfInvention | Reductive dechlorination of 1,1,1,2-tetrafluoro-2 chloroethane |
abstract | PURPOSE: To easily obtain 1,1,1,2-tetrafluoroethane in a high conversion ratio by subjecting 1,1,1,2-tetrafluoro-2-chloroethane to reductive dechlorination in a specific solvent at specific temp. by using Zn in the presence of a proton source. n CONSTITUTION: 1,1,1,2-tetrafluoro-2-chloroethane is subjected to reductive dechlorination for 5 min-20 hr in a polar aprotic solvent such as dimethylformamide in the presence of a proton source such as pyridinium acetate at 250°C under a pressure of 1-200 atm by using finely divided elemental Zn or metal Zn to obtain the objective compd. useful as a solvent, a propellant, especially, a cooling medium. As the above mentioned proton source, an ammonium component represented by formula NR 3 H + [wherein R is H, 1-4C alkyl or (substd.)pyridinium] and ammonium carboxylate composed of a carboxylate component of 1-8C alkyl or aryl such as acetate are pref. used. n COPYRIGHT: (C)1990,JPO |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-H0251848-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-2015209397-A |
priorityDate | 1989-01-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 32.