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filingDate 1988-12-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1270b3eec034cfc3366a22ff0622a54f
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publicationDate 1990-01-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H02230-A
titleOfInvention Preparation of 1-nitroanthraquinone
abstract PURPOSE: To obtain 1-nitroanthraquinone of high purity, important as a dye intermediate in a high yield by subjecting 1-nitro-tetrahydroanthraquinone obtained by reacting 5-nitro-1,4-naphthoquinone with butadiene in a two-stage oxidation reaction. n CONSTITUTION: 1-nitro-5,8,11,12-tetrahydroanthraquinone obtained by reacting 5-nitro-1,4-naphthoquinone with butadiene is oxidized to 1-nitro-5,8- dihydroanthraquinone at a temp. of 5-100°C by using oxygen, an inorg. peroxide compd. (e.g.; perborate, persulfate) or metal oxide (suitably, manganese dioxide) as an oxidizing agent and this intermediate is oxidized at temp. slightly higher than the above mentioned reaction temp., pref., at a temp. of 20-160°C by using one of the above mentioned oxidizing agents to obtain 1-nitroanthraquinone. It is pref. to further subject this product to post-treatment by an acid (suitably, nitric acid) having oxidizing action. n COPYRIGHT: (C)1990,JPO
priorityDate 1987-12-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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