http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-H02172967-A

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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C323-20
filingDate 1988-12-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_a677201f71f9829c609bace0329d46e0
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1bd1a39ff54f1fb4074797a22a73a272
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publicationDate 1990-07-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H02172967-A
titleOfInvention Production of carbonic acid ester
abstract PURPOSE: To obtain the subject compound useful as an introducing reagent in high yield and efficiency in an easily separable state by reacting di-t-butyl dicarbonate with a p-dialkyl-sulfoniophenol in the presence of a specific amine. n CONSTITUTION: The objective carbonic acid ester of formula II (t-Bu is t-butyl) can be produced by reacting d-t-butyl dicarbonate with a p-dialkylsulfoniophenol of formula I (R 1 and R 2 are alkyl; Y - is halogen anion, perchlorate radical, etc.; X is H, halogen, etc.) in the presence of three kinds of amines comprising secondary amines having a structure containing two secondary alkyl groups bonded to N atom (e.g. dicyclohexylamine or di-sec-butylamine) or tertiary amines having the above structure (e.g. dicyclo-hexylmethylamine) and pyridine derivatives having substituents at 2 and 6-sites (e.g. 2,6-lutidine). The compound of formula II exhibits excellent acylating action in aqueous solution. n COPYRIGHT: (C)1990,JPO&Japio
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-2006131612-A
priorityDate 1988-12-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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