http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-H02169551-A

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filingDate 1989-10-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_351d88868ebefb7476497d9fdb023cc8
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publicationDate 1990-06-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H02169551-A
titleOfInvention Production of dinitrotoluene
abstract PURPOSE: To efficiently obtain dinitrotoluene without generating the problem caused by the use of conc. sulfuric acid by reacting mononitrotoluene and nitric acid in a liquid phase in the presence of a specific inorg. acidic solid. n CONSTITUTION: In the presence of an inorg. acidic solid containing at least one kind of a component selected from the group consisting of orthophosphoric acid, pyrophosphoric acid, metaphosphoric acid, first phosphate, second phosphate, orthophosphate and pyrophosphate of a metal capable of forming a cation having positive charge of 1-5, especially, 3-5, mononitrotoluene and nitric acid are reacted at 40-100°C in a mol ratio of nitric acid/mononitrotoluene of 0.1-10 to obtain dinitrotoluene. This reaction is pref. performed in the presence of 0.5-5 mol, per 1 g of a solid, of a diluent (e.g.; perfluorodecalin, methylene chloride). n COPYRIGHT: (C)1990,JPO
priorityDate 1988-10-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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