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filingDate 1988-11-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_565b74b5bcea4691dc6ed27e4179c148
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publicationDate 1990-05-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H02138191-A
titleOfInvention Preparation of n-phosphonomethyl glycine
abstract PURPOSE: To obtain a compound useful as herbicide simply in a high yield by a method in which N-phosphonomethyl-oxazolidone is hydrolyzed in water, by-produced CO 2 is removed, an alkali and a catalyst are added, and the hydrolyzate is oxidized. n CONSTITUTION: First, the aqueous solution of N-phosphonomethyl-2-oxazolidone is reacted to hydrolyzed the oxazolidone group and to produce CO 2 , and the reaction is continued until the oxazolidone is converted completely into N- phosphonomethyl ethanolamine or its cyclic internal ester (hereafter called hydrolyzate). Next, after by-produced CO 2 being removed, an acid in the phosphonomethyl group of the hydrolyzate is neutralized. An aqueous alkali in excess of at least one mole to the hydrolyzate and a catalyst selected from Cd, Cu, Zn, Pd, Pt, their salts, oxides, and hydroxides are added into the reaction system, the hydrolyzate is oxidized at 200-300°C, and the reaction mixture is acidified to obtain the objective intended compound. n COPYRIGHT: (C)1990,JPO
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