http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-H02104554-A

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filingDate 1988-10-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_912f2158c823ccbf13e3477f3858572d
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9f694ee02e60c8fc42aa20cfa629c697
publicationDate 1990-04-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H02104554-A
titleOfInvention Production of esters
abstract PURPOSE: To obtain the subject compound useful as intermediate of perfume or medicine, etc., in short time, high purity and high yield without using highly excessive alcohol or solvent by reacting alcohol with carboxylic acid in the presence of thionyl chloride of specific amount to said acid. n CONSTITUTION: Carboxylic acid (e.g., acetic acid, propionic acid or butyric acid) is reacted with alcohol (1-6C monohydric alcohol, e.g., methanol, ethanol or isopropanol) to obtain esters in the presence of thionyl chloride of 0.1-0.5 equiv. time, preferably about 0.2 equiv. time to said acid. By said method, esterification reaction is initiated by the presence of catalytic amount of thionyl chloride and further, hydrogen chloride and CO 2 derived from thionyl chloride act as acid catalyst and equilibrium reaction of esterification is transferred to forming system, thus esters are quantitatively obtained with only using more than equivalent of alcohol without specially removing generated water. n COPYRIGHT: (C)1990,JPO&Japio
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-2008303173-A
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/KR-100525358-B1
priorityDate 1988-10-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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